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Structural Investigations on Enantiopure P–OP Ligands: A High‐Performing P–OP Ligand for Rhodium‐Catalysed Hydrogenations
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2018-04-11 , DOI: 10.1002/ejoc.201701760
Héctor Fernández-Pérez 1 , Bugga Balakrishna 1 , Anton Vidal-Ferran 1, 2
Affiliation  

A second generation of phosphine–phosphite (P–OP) ligands, incorporating a larger phosphite group than previous P–OP ligand designs, led to very efficient catalysts for the Rh‐catalyzed enantioselective hydrogenation of a diverse array of substrates (11 examples, 93–99 % ee, mean value of 98 % ee).
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中文翻译:

对映纯P-OP配体的结构研究:铑催化加氢的高性能P-OP配体

第二代膦-亚磷酸酯(P-OP)配体,与以前的P-OP配体设计相比,具有更大的亚磷酸酯基团,从而为多种底物的Rh催化对映选择性氢化提供了非常有效的催化剂(11个实例,93 –99%ee,平均值为98%ee)。
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更新日期:2018-04-11
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