当前位置: X-MOL 学术Organometallics › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Activation of Carbon–Hydrogen Bonds via 1,2-RH-Addition/-Elimination to Early Transition Metal Imides
Organometallics ( IF 2.8 ) Pub Date : 2018-02-05 00:00:00 , DOI: 10.1021/acs.organomet.7b00753
Peter T. Wolczanski 1
Affiliation  

A tutorial addressing the activation of carbon–hydrogen bonds via the 1,2-RH-addition to high oxidation state, early metal XnM═NR complexes is described. Details regarding the reverse 1,2-RH-elimination from Xn(R′)M–NHR, are also presented. The overall process is discussed as follows: (1) electrophilicity and electronics; (2) general mechanism; (3) kinetics of 1,2-RH-elimination; (4) periodic trends; (5) alkane complexes; (6) kinetic isotope effects (KIEs); (7) RH activation selectivities; and (8) future directions.

中文翻译:

通过1,2-RH加/消除早期过渡金属酰亚胺的碳氢键活化

阿教程经由1,2- RH-除了高氧化态,早期金属X的寻址碳-氢键的活化Ñ M═NR络合物进行说明。还提供了有关从X n(R')M–NHR进行1,2-RH反向消除的详细信息。整个过程讨论如下:(1)亲电性和电子性;(2)一般机制;(3)消除1,2-RH的动力学;(4)周期性趋势;(5)烷烃配合物;(6)动力学同位素效应(KIEs);(7)RH活化选择性;(8)未来方向。
更新日期:2018-02-05
down
wechat
bug