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High-Nuclearity Lanthanide-Containing Clusters as Potential Molecular Magnetic Coolers
Accounts of Chemical Research ( IF 18.3 ) Pub Date : 2018-02-02 00:00:00 , DOI: 10.1021/acs.accounts.7b00579
Xiu-Ying Zheng 1 , Xiang-Jian Kong 1 , Zhiping Zheng 2, 3 , La-Sheng Long 1 , Lan-Sun Zheng 1
Affiliation  

High-nuclearity cluster-type metal complexes are a unique class of compounds, many of which have aesthetically pleasing molecular structures. Their interesting physical and chemical properties arise primarily from the electronic and/or magnetic interplay between the component metal ions. Among the extensive studies in the past two decades, those on lanthanide-containing clusters, lanthanide-exclusive or heterometallic with transition metal elements, are most notable. The research was driven by both the synthetic challenges for these generally elusive species and their intriguing magnetic properties, which are useful for the development of energy-efficient and environmentally friendly magnetic cooling technologies.

中文翻译:

高核含量的含镧系元素团簇作为潜在的分子磁冷却器

高核簇型金属络合物是一类独特的化合物,其中许多具有美观的分子结构。它们有趣的物理和化学性质主要来自组分金属离子之间的电子和/或磁性相互作用。在过去的二十年中,广泛的研究中,最著名的是含镧系元素的簇,镧系元素专有的或具有过渡金属元素的杂金属。这些普遍难以捉摸的物种面临的合成挑战及其引人入胜的磁性,都对这项研究起到了推动作用,这些特性对于开发节能环保的磁性冷却技术很有用。
更新日期:2018-02-02
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