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Nitrosotetrazolium‐Catalyzed Aerobic Oxidation of Alcohols to the Corresponding Carbonyl Compounds
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2018-03-22 , DOI: 10.1002/ejoc.201701662
Yuta Matsukawa 1 , Tsunehisa Hirashita 1 , Shuki Araki 1
Affiliation  

The nitrosotetrazolium‐catalyzed aerobic oxidation of alcohols is reported. By using catalytic amounts of nitrosotetrazolium species 1 and nitric acid, various alcohols were oxidized to the corresponding carbonyl compounds under ambient air or oxygen conditions. A mechanism involving a nitroso/NOx catalytic cycle is proposed.
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中文翻译:

亚硝基四唑鎓催化的酒精好氧氧化为相应的羰基化合物

据报道,亚硝基四唑鎓催化的酒精好氧氧化反应。通过使用催化量的亚硝基四唑鎓盐物种1和硝酸,在环境空气或氧气条件下,各种醇被氧化为相应的羰基化合物。提出了涉及亚硝基/ NO x催化循环的机理。
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更新日期:2018-03-22
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