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Excellent catalytic performance for methanol to olefins over SAPO-34 synthesized by controlling hydrothermal temperature
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-01-31 , DOI: 10.1016/j.catcom.2018.01.033
Xiaotong Wang , Rui Li , Syed ul Hasnain Bakhtiar , Fulong Yuan , Zhibin Li , Yujun Zhu

A facile way to synthesize a series of SAPO-34 zeolites was developed by using the mixed templates of morpholine and TEAOH with changing the temperature. Among these samples, SAPO-34-210 exhibited with the longest lifetime and the highest selectivity to light olefin for methanol to olefin (MTO) reaction. The characterizations suggested that SAPO-34-210 has unique Si distribution due to much more amount of TEAOH introduced into structure, which resulted in the excellent catalytic performance.



中文翻译:

通过控制水热温度合成的SAPO-34具有优异的甲醇制烯烃催化性能

通过使用吗啉和TEAOH的混合模板随温度变化,开发了一种简便的合成一系列SAPO-34沸石的方法。在这些样品中,SAPO-34-210表现出最长的寿命和对甲醇到烯烃(MTO)反应的对轻烯烃的最高选择性。表征表明,由于引入结构中的TEAOH的数量更多,SAPO-34-210具有独特的Si分布,这导致了出色的催化性能。

更新日期:2018-01-31
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