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Confining SnS2 Ultrathin Nanosheets in Hollow Carbon Nanostructures for Efficient Capacitive Sodium Storage
Joule ( IF 39.8 ) Pub Date : 2018-01-27 , DOI: 10.1016/j.joule.2018.01.004
Yuhan Liu , Xin-Yao Yu , Yongjin Fang , Xiaoshu Zhu , Jianchun Bao , Xiaosi Zhou , Xiong Wen (David) Lou

Tin disulfide (SnS2) is a promising anode material for sodium-ion batteries because of its high specific capacity. However, the low conductivity and large volume change during reaction with Na+ ions greatly limit its practical application. Herein, a multistep templating method has been exploited for the rational design and synthesis of SnS2 nanosheets confined in carbon nanotubes (SnS2@CNTs). To demonstrate the universality of this method, SnS2 nanosheets confined in carbon nanoboxes (SnS2@CNBs) and hollow carbon nanospheres (SnS2@CNSs) have also been synthesized by simply changing the template in the reaction system. Due to their unique structural merits, the SnS2@CNTs, SnS2@CNBs, and SnS2@CNSs show improved sodium storage performance in terms of high specific capacity, good cycling stability, and superior rate capability.



中文翻译:

将SnS 2超薄纳米片限制在中空碳纳米结构中,以有效地储存电容性钠

二硫化锡(SnS 2)因其高比容量而成为钠离子电池的有希望的负极材料。但是,与Na +离子反应过程中电导率低且体积变化大,极大地限制了其实际应用。在本文中,已经开发了一种多步骤模板方法用于合理设计和合成限制在碳纳米管(SnS 2 @CNTs)中的SnS 2纳米片。为了证明此方法的通用性,将SnS 2纳米片限制在碳纳米盒(SnS 2 @CNBs)和中空碳纳米球(SnS 2也可以通过简单地改变反应系统中的模板来合成@CNSs。由于其独特的结构优点,SnS 2 @ CNTs,SnS 2 @CNBs和SnS 2 @CNSs在高比容量,良好的循环稳定性和优异的倍率性能方面显示出改善的钠储存性能。

更新日期:2018-01-27
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