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A facile dip-coating method for the preparation of separable MoS2 sponges and their high-efficient adsorption behaviors of Rhodamine B†
Inorganic Chemistry Frontiers ( IF 7 ) Pub Date : 2018-01-29 00:00:00 , DOI: 10.1039/c8qi00012c
Yueyun Fang 1, 2, 3, 4, 5 , Qizhang Huang 1, 2, 3, 4, 5 , Pengyi Liu 6, 7, 8, 9, 10 , Jifu Shi 6, 7, 8, 9, 10 , Gang Xu 1, 2, 3, 4, 5
Affiliation  

Molybdenum disulfide (MoS2) nanoflowers synthesized by a hydrothermal route were successfully grafted on a melamine-formaldehyde sponge through a facile dip-coating method to form MoS2 nanoflowers sponges. The MoS2 sponges exhibited high-efficient adsorption performance to cationic dye, Rhodamine B (RhB), with a maximum adsorption capacity of 104.78 mg RhB g−1 product (equal to 213.84 mg RhB g−1 MoS2 by conversion) within 60 min, which was primarily attributed to the strong electrostatic interactions between electronegative MoS2 nanoflowers and positively charged RhB molecules. The equilibrium adsorption and kinetics data fitted well with the Sips isotherm model and the pseudo-second-order kinetic model, respectively. The recyclability experiments showed that the MoS2 sponge adsorbent could be reused for 10 times with above 86.7% of the adsorption capacity retained. More remarkably, the as-prepared sponge adsorbent can be separated from the dye solution easily through a simple salvage instead of any tedious centrifugation or filtration processes. Thus, the separable MoS2 sponge adsorbent with remarkable adsorption capacity and excellent reusability for organic dyes shows promise for large scale water remediation in the future.

中文翻译:

一种简便的浸涂法制备可分离的MoS 2海绵及其对若丹明B †的高效吸附性能

将水热法合成的二硫化钼(MoS 2)纳米花成功地通过简便的浸涂法接枝在三聚氰胺-甲醛海绵上,形成了MoS 2纳米花海绵。MoS 2海绵在60分钟内对阳离子染料若丹明B(RhB)表现出高效的吸附性能,最大吸附容量为104.78 mg RhB g -1产物(换算为213.84 mg RhB g -1 MoS 2)。 ,这主要归因于负电MoS 2之间的强静电相互作用纳米花和带正电的RhB分子。平衡吸附和动力学数据分别与Sips等温线模型和拟二阶动力学模型很好地拟合。可回收性实验表明,MoS 2海绵吸附剂可以重复使用10次,保留了86.7%的吸附能力。更显着的是,可以通过简单的补救方法而不是任何繁琐的离心或过滤过程,将制备的海绵吸附剂轻松地从染料溶液中分离出来。因此,具有优异的吸附能力和优异的有机染料可重复使用性的可分离的MoS 2海绵吸附剂显示了未来大规模水修复的前景。
更新日期:2018-01-29
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