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Mesoporous fullerene C70 cubes with highly crystalline frameworks and unusually enhanced photoluminescence properties†
Materials Horizons ( IF 13.3 ) Pub Date : 2018-01-26 00:00:00 , DOI: 10.1039/c7mh00954b Partha Bairi 1, 2, 3, 4 , Tohru Tsuruoka 1, 2, 3, 4 , Somobrata Acharya 5, 6, 7, 8 , Qingmin Ji 1, 2, 3, 4, 9 , Jonathan P. Hill 1, 2, 3, 4 , Katsuhiko Ariga 1, 2, 3, 4, 10 , Yusuke Yamauchi 11, 12, 13, 14, 15 , Lok Kumar Shrestha 1, 2, 3, 4
Materials Horizons ( IF 13.3 ) Pub Date : 2018-01-26 00:00:00 , DOI: 10.1039/c7mh00954b Partha Bairi 1, 2, 3, 4 , Tohru Tsuruoka 1, 2, 3, 4 , Somobrata Acharya 5, 6, 7, 8 , Qingmin Ji 1, 2, 3, 4, 9 , Jonathan P. Hill 1, 2, 3, 4 , Katsuhiko Ariga 1, 2, 3, 4, 10 , Yusuke Yamauchi 11, 12, 13, 14, 15 , Lok Kumar Shrestha 1, 2, 3, 4
Affiliation
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Here we report the synthesis of new mesoporous crystalline fullerene (C70) cubes (MCFCs) at a liquid–liquid interface between tert-butyl alcohol (TBA) and a solution of C70 in mesitylene under mild heat treatment. The highly crystalline pore walls of the MCFCs result in enhanced electrochemical and photoluminescence properties, which differ from pristine C70 and crystalline C70 cubes lacking mesopores.
中文翻译：
介孔富勒烯C 70立方体，具有高度结晶的骨架和异常增强的光致发光性能†
在这里，我们报告了在温和热处理下，叔丁醇（TBA）与C 70的均三甲苯溶液之间的液-液界面，合成了新的介孔晶体富勒烯（C 70）立方（MCFC）。MCFC的高度结晶的孔壁导致增强的电化学和光致发光特性，这与原始C 70和缺少中孔的结晶C 70立方体不同。
更新日期：2018-01-26
中文翻译：
介孔富勒烯C 70立方体，具有高度结晶的骨架和异常增强的光致发光性能†
在这里，我们报告了在温和热处理下，叔丁醇（TBA）与C 70的均三甲苯溶液之间的液-液界面，合成了新的介孔晶体富勒烯（C 70）立方（MCFC）。MCFC的高度结晶的孔壁导致增强的电化学和光致发光特性，这与原始C 70和缺少中孔的结晶C 70立方体不同。
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