Two isomorphous azide/formate Mn(ii) coordination polymers show spin-canted antiferromagnetism only in the formate system†,Inorganic Chemistry Frontiers

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Two isomorphous azide/formate Mn(ii) coordination polymers show spin-canted antiferromagnetism only in the formate system†
Inorganic Chemistry Frontiers ( IF 7 ) Pub Date : 2018-01-19 00:00:00 , DOI: 10.1039/c7qi00789b
Jiao-Yang Wang _{1,

2,

3,

4,

5} , Qian Yang _{4,

6,

7,

8} , Yi-Quan Zhang _{9,

10,

11,

12,

13} , Guang-Bo Che _{8,

14,

15,

16,

17} , Jiong-Peng Zhao _{1,

2,

3,

4,

5} , Fu-Chen Liu _{1,

2,

3,

4,

5}

Affiliation

School of Chemistry and Chemical Engineering
TKL of Organic Solar Cells and Photochemical Conversion
Tianjin University of Technology
Tianjin
300384 China
School of Science
Tianjin University of Science & Technology
China
Jiangsu Key Laboratory for NSLSCS
School of Physical Science and Technology
Nanjing Normal University
Nanjing 210023
P. R. China
Key Laboratory of Preparation of Environmental Friendly
Jilin Normal University
Ministry of Education
Changchun

Two isostructural 3D complexes [Mn(L)(N₃)·MeOH]_n (1) and [Mn(L)(HCO₂)·MeOH]_n (2) (HL = pyrazine-2-carboxylic acid) were synthesized by using a solvothermal method. Magnetic studies indicate that 1 was a strong antiferromagnet, whereas 2 was a weak antiferromagnet with T_N 38.5 K.

中文翻译：

两种同构的叠氮化物/甲酸酯Mn（ii）配位聚合物仅在甲酸酯体系中显示出自旋倾斜的反铁磁性†

两种同构3D配合物[Mn（L）（N ₃）·MeOH] _n（1）和[Mn（L）（HCO ₂）·MeOH] _n（2）（HL =吡嗪-2-羧酸）合成使用溶剂热法。磁性研究表明1是强反铁磁体，而2是T _N 38.5 K的弱反铁磁体。

更新日期：2018-01-19

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