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Twisted Charge‐Transfer Antennae for Ultra‐Bright Terbium(III) and Dysprosium(III) Bioprobes
Chemistry - A European Journal ( IF 4.3 ) Pub Date : 2018-02-05 , DOI: 10.1002/chem.201705933
Anh Thy Bui 1 , Amandine Roux 1 , Alexei Grichine 2 , Alain Duperray 2 , Chantal Andraud 1 , Olivier Maury 1
Affiliation  

The design of original twisted charge transfer antennae in which a non‐planar geometry is enforced thanks to one or two bulky ortho‐Me substituents allows us to prepare the corresponding ultra‐bright TbIII and DyIII bioprobes. The brightness of the TbIII derivative compares well with that of the benchmark Tb‐Lumi4 complex. The first bio‐imaging experiments with a DyIII luminescent bioprobe are also reported.

中文翻译:

超亮Ter(III)和Dy(III)生物探针的扭曲电荷转移天线

原始的扭曲电荷转移天线的设计由于一个或两个庞大的邻-我取代基而具有非平面几何形状,这使我们能够制备相应的超亮Tb III和Dy III生物探针。Tb III衍生物的亮度与基准Tb-Lumi4复合物的亮度相当。还报道了使用Dy III发光生物探针进行的第一批生物成像实验。
更新日期:2018-02-05
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