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sp3 C–H activation via exo-type directing groups
Chemical Science ( IF 8.4 ) Pub Date : 2018-01-17 00:00:00 , DOI: 10.1039/c7sc04768a
Yan Xu 1 , Guangbin Dong 1
Affiliation  

The application of exo-type directing groups (DGs) has led to the discovery of a wide range of novel C(sp3)–H activation methods, which allow efficient and site-selective functionalization of alcohol and amide derivatives. In this mini-review we discuss the challenges of this field and summarize the achievements, including DG designs, reaction discoveries and mechanistic studies.

中文翻译:

通过外型导向基团激活 sp3 C-H

外型导向基团 (DGs)的应用导致发现了广泛的新型 C(sp 3 )-H 活化方法,这些方法允许对醇和酰胺衍生物进行有效和位点选择性的官能化。在这篇小型评论中,我们讨论了该领域的挑战并总结了成就,包括 DG 设计、反应发现和机理研究。
更新日期:2018-01-17
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