International Journal of Hydrogen Energy ( IF 7.2 ) Pub Date : 2018-01-17 , DOI: 10.1016/j.ijhydene.2017.12.140 Geng Li , Hongyun Jin , Liangqi Gui , Beibei He , Ling Zhao
Nano composite of Ruddlesden-Popper electrocatalyst-oxygen ionic conductor, (Pr0.9La0.1)2(Ni0.74Cu0.21Nb0.05)O4+δ (PLNCN)-Ce0.9Gd0.1O2−δ (GDC), is developed as composite cathode for intermediate temperature solid oxide fuel cells (IT-SOFCs) via a infiltration way. The electrochemical behavior of PLNCN-GDC nanostructured electrode is assessed with respect to infiltration loading and oxygen partial pressure. The optimized PLNCN loading can improve charge transfer dynamics for electrochemical oxygen reduction reaction, thus promoting cathode performance. Importantly, the encouraging results of single cell highlight high activity and good CO2 tolerance of PLNCN-GDC nanostructured cathode.
中文翻译:
(Pr 0.9 La 0.1)2(Ni 0.74 Cu 0.21 Nb 0.05)O 4 +δ- Ce 0.9 Gd 0.1 O2 -δ(GDC)作为中温固体氧化物燃料电池的活性和耐CO 2纳米复合阴极
Ruddlesden-Pop电催化剂-氧离子导体的纳米复合材料,(Pr 0.9 La 0.1)2(Ni 0.74 Cu 0.21 Nb 0.05)O 4 +δ(PLNCN)-Ce 0.9 Gd 0.1 O 2−δ(GDC)通过渗透方式开发为中温固体氧化物燃料电池(IT-SOFC)的复合阴极。关于渗透负荷和氧分压,评估了PLNCN-GDC纳米结构电极的电化学行为。优化的PLNCN负载量可以改善用于电化学氧还原反应的电荷转移动力学,从而提高阴极性能。重要的是,单电池的令人鼓舞的结果突出了PLNCN-GDC纳米结构阴极的高活性和良好的CO 2耐受性。