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Histaminol and its complexes with copper(II) - studies in solid state and solution
European Journal of Inorganic Chemistry ( IF 2.3 ) Pub Date : 2018-03-25 , DOI: 10.1002/ejic.201701411
Piotr Maślewski 1 , Dariusz Wyrzykowski 2 , Maciej Witwicki 3 , Anna Dołęga 1
Affiliation  

Histaminol [4(5)-(B-hydroxyethyl)imidazole, 4-(1H-imidazol-2-yl)ethanol, L] is an analogue of histamine and its minor metabolite. So far its properties have not been studied in detail due to the synthetic difficulties. Here, the structure and acid-base properties of histaminol, as well as the results of studies on its copper(II) complexes in solid state and aqueous solution are reported. Stability constants of the histaminol–CuII sys- 11 tem are measured and each stage of the complex formation is illustrated with the relevant crystal structure and the EPR spectrum.

中文翻译:

组胺醇及其与铜 (II) 的配合物 - 固态和溶液研究

组胺醇 [4(5)-(B-羟乙基)咪唑,4-(1H-咪唑-2-基)乙醇,L]是组胺及其次要代谢物的类似物。迄今为止,由于合成困难,尚未对其性质进行详细研究。在这里,报告了组胺醇的结构和酸碱性质,以及其在固态和水溶液中的铜 (II) 配合物的研究结果。测量组胺醇-CuII 系统的稳定性常数 11 并用相关的晶体结构和 EPR 光谱说明复合物形成的每个阶段。
更新日期:2018-03-25
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