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Catalysing water oxidation using nature’s metal
Nature Catalysis ( IF 37.8 ) Pub Date : 2018-01-08 , DOI: 10.1038/s41929-017-0013-1
Gary W. Brudvig

Catalysing water oxidation using nature’s metal

Catalysing water oxidation using nature’s metal, Published online: 08 January 2018; doi:10.1038/s41929-017-0013-1

In nature, a manganese catalyst is used for photosynthetic water oxidation, but efforts to develop artificial manganese-based counterparts have been hampered by the lability of manganese complexes. By using a bulky and hydrophilic ligand, a water-soluble Mn12 complex is found to be a stable and efficient water oxidation electrocatalyst.


中文翻译:

使用天然金属催化水氧化

使用天然金属催化水氧化

使用天然金属催化水氧化,在线发布:2018年1月8日; doi:10.1038 / s41929-017-0013-1

在自然界中,锰催化剂用于光合作用的水氧化,但是锰配合物的不稳定性阻碍了开发人造锰基对应物的努力。通过使用大体积且亲水的配体,发现水溶性Mn12络合物是稳定且有效的水氧化电催化剂。
更新日期:2018-01-16
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