Catalytic hydrogenation and dehydrogenation reactions form the core of the modern chemical industry. This vast class of reactions is found in any part of chemical synthesis starting from the milligram-scale exploratory organic chemistry to the multi-ton base chemicals production. Noble metal catalysis has long been the key driving force in enabling these transformations with carbonyl substrates and their nitrogen-containing counterparts. This review is aimed at introducing the reader to the remarkable progress made in the last three years in the development of base metal catalysts for hydrogenations and dehydrogenative transformations.

中文翻译：

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非贵金属（钴，铁和锰）促进的催化（脱）氢反应：新兴领域的最新进展†

催化加氢和脱氢反应是现代化学工业的核心。从毫克级的探索性有机化学到多吨基础化学品的生产，在化学合成的任何部分中都可以找到这类广泛的反应。长期以来，贵金属催化一直是通过羰基底物及其含氮对应物实现这些转化的关键驱动力。这篇综述旨在向读者介绍在过去三年中，用于氢化和脱氢转化的贱金属催化剂的开发取得的显著进展。