A Pt(II)phenylbipyridine complex 1, possessing phenylisoxazoles, long alkyl chains, and chiral alkyl chains, was synthesized. Complex 1 formed a stacked assembly in chloroform, self-assembled in a cooperative manner in methylcyclohexane (MCH), and gelled in higher alcohols and dodecane. In the nucleation regime, 1 assembled via a Pt–Pt interaction, which was demonstrated by the metal–metal-to-ligand charge transfer (MMLCT) emission band of the assembly. In the elongation regime, 1 displayed aggregation-induced emission enhancement (AIEE) character. The assembly of 1 formed in MCH was chiroptically non-active, suggesting that the assembly was non-helical. Complex 1 also exhibited strong AIEE and circularly polarized luminescence (CPL) with an anisotropic factor (g_lum) of 0.011 in 1-decanol gel, indicating that a chiral assembly was formed in the gel.

中文翻译：

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基于具有苯异恶唑的Pt（ii）配合物的圆偏振发光有机凝胶†

合成了具有苯基异恶唑，长烷基链和手性烷基链的Pt（II）苯基联吡啶配合物1。配合物1在氯仿中形成堆叠的组装体，在甲基环己烷（MCH）中以协同方式自组装，并在高级醇和十二烷中凝胶化。在成核状态下，1通过Pt-Pt相互作用组装，这通过装配体的金属-金属-配体电荷转移（MMLCT）发射带来证明。在伸长状态下，1显示出聚集诱导的发射增强（AIEE）特性。组装1在妇幼保健院形成的是脊椎不活动的，表明该程序集是非螺旋的。配合物1在1-癸醇凝胶中还表现出较强的AIEE和各向异性因子（g _lum）为0.011的圆偏振发光（CPL），表明在凝胶中形成了手性组装体。