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The directional character of the piperazine double addition product, e{N(CH2CH2)2N}2C60, as a building block for forming crystalline fullerene polymers†
CrystEngComm ( IF 3.1 ) Pub Date : 2018-01-15 00:00:00 , DOI: 10.1039/c7ce02117h
Amineh Aghabali 1, 2, 3, 4 , Sharon Jun 1, 2, 3, 4 , Marilyn M. Olmstead 1, 2, 3, 4 , Alan L. Balch 1, 2, 3, 4
Affiliation  

The piperazine double addition product, e{N(CH2CH2)2N}2C60, has its donor atoms positioned to bind Lewis acids in a defined fashion in two orthogonal directions. It has been used to construct crystalline, one- and two-dimensional polymers through reactions with diiodine and the rhodium(II) acetate dimer.

中文翻译:

哌嗪双加成产物e {N(CH 2 CH 22 N} 2 C 60的方向特性,作为形成结晶富勒烯聚合物的基础材料

哌嗪双加成产物e {N(CH 2 CH 22 N} 2 C 60的给体原子定位成在两个正交方向上以定义的方式结合路易斯酸。它已通过与二碘和乙酸铑(II)二聚体反应来构建结晶的一维和二维聚合物。
更新日期:2018-01-15
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