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Efficient Catalytic Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid by Magnetic Laccase Catalyst
ChemBioChem ( IF 3.2 ) Pub Date : 2018-02-16 , DOI: 10.1002/cbic.201800008
Ke-Feng Wang 1, 2, 3 , Chun-lei Liu 4 , Kun-yan Sui 1 , Chen Guo 2 , Chun-Zhao Liu 1, 2
Affiliation  

Cleaning up catalysis: There is a great need for the eco‐efficient and sustainable oxidation of bio‐based chemicals by using clean catalysts. In this study, magnetic laccase catalyst with TEMPO as the mediator showed high activity in the oxidation of 5‐hydroxymethylfurfural (HMF). Interesting and promising results were obtained, with 90.2 % yield of 2,5‐furandicarboxylic acid (FDCA) and complete HMF conversion.
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中文翻译:

磁性漆酶催化将5-羟基甲基糠醛有效催化氧化为2,5-呋喃二甲酸

清除催化:迫切需要使用清洁的催化剂对生物基化学品进行生态高效和可持续的氧化。在这项研究中,以TEMPO为介体的磁性漆酶催化剂在5-羟甲基糠醛(HMF)的氧化中表现出高活性。获得了有趣而有希望的结果,2,5-呋喃二甲酸(FDCA)的产率为90.2%,并完成了HMF的转化。
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更新日期:2018-02-16
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