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Cover Feature: Cyanido-Bridged FeII–MI Dimetallic Hofmann-Like Spin-Crossover Coordination Polymers Based on 2,6-Naphthyridine (Eur. J. Inorg. Chem. /2018)
European Journal of Inorganic Chemistry ( IF 2.3 ) Pub Date : 2018-01-15 , DOI: 10.1002/ejic.201701490
Lucía Piñeiro-López 1 , Francisco Javier Valverde-Muñoz 1 , Maksym Seredyuk 1, 2 , Carlos Bartual-Murgui 1 , M. Carmen Muñoz 3 , José Antonio Real 1
Affiliation  

Thumbnail image of graphical abstract

The Cover Feature shows the thermal variations of the χMT product (χM: magnetic susceptibility, T: temperature) and the specific heat (ΔCp) associated with the spin crossover of the triply interpenetrated Hofmann-type coordination polymer {Fe(2,6-naphthypyridine)[Ag(CN)2][Ag2(CN)3]}. The background is the spectacular natural scenery of the “Trou de Fer” (Iron Hole) on Reunion Island. The waterfall follows the steep slope of a collapsed crater while χMT drops/climbs as temperature decreases/increases following the variation in entropy, which drives the spin crossover phenomenon. More information can be found in the Full Paper by J. A. Real et al.



中文翻译:

封面人物:基于2,6-萘啶的氰基桥接FeII-MI双金属霍夫曼样自旋交叉配位聚合物(Eur。J. Inorg。Chem。/ 2018)

图形摘要的缩略图图像

封面特征示出了的热变化χ中号Ť产物(χ中号:磁化率,Ť:温度)和比热(Δ Ç p与三重的自旋交叉相关联的)互穿霍夫曼型配位聚合物{的Fe( 2,6-萘吡啶)[Ag(CN)2 ] [Ag 2(CN)3 ]}。背景是留尼汪岛“铁洞”(铁洞)壮观的自然风光。瀑布如下而塌缩痕的陡坡χ中号Ť随着熵的变化,温度降低/升高,温度下降/上升,这驱动了自旋交叉现象。可以在JA Real等人的《全文》中找到更多信息

更新日期:2018-01-15
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