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Nickel and Copper‐Catalyzed Carbonylation Reaction of Organoboranes
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2018-01-31 , DOI: 10.1002/ajoc.201700681
Elham Etemadi-Davan 1 , Nasser Iranpoor 1 , Pourya Arshad 1
Affiliation  

Carbonylation of arylboronic acid derivatives employing Cr(CO)6 as the carbonyl source and NiCl2(dmg)/4,4′‐bipy as the catalyst under air without applying external oxidant has been reported for the amide and ester synthesis (dmg=dimethylgloxime; bipy=bipyridine). Moreover, CHCl3 was also used as another carbonyl source for the amide synthesis with CuI/1,10‐phenanthroline catalytic system.

中文翻译:

镍和铜催化有机硼烷的羰基化反应

对于酰胺和酯的合成,已经报道了使用Cr(CO)6作为羰基来源和NiCl 2(dmg)/ 4,4'-bipy作为催化剂在空气中不应用外部氧化剂的情况下芳基硼酸衍生物的羰基化反应(dmg =二甲基gloxime ; bipy = bipyridine)。此外,CHCl 3还用作CuI / 1,10-菲咯啉催化体系合成酰胺的另一种羰基来源。
更新日期:2018-01-31
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