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Aerobic Photooxidative Synthesis of β‐Alkoxy Monohydroperoxides Using an Organo Photoredox Catalyst Controlled by a Base
Chemistry - An Asian Journal ( IF 4.1 ) Pub Date : 2018-02-01 , DOI: 10.1002/asia.201701742
Yuya Asano 1 , Yoshitomo Nagasawa 1 , Eiji Yamaguchi 1 , Akichika Itoh 1
Affiliation  

Transition‐metal‐free synthesis of β‐alkoxy monohydroperoxides via aerobic photooxidation using an acridinium photocatalyst was developed. This method enables the synthesis of some novel hydroperoxides. The peroxide source is molecular oxygen, which is cost‐effective and atomically efficient. Magnesium oxide plays an important role as a base in the catalytic system.

中文翻译:

碱控制有机光氧化还原催化剂的好氧光氧化合成β-烷氧基单氢过氧化物

开发了使用cri啶光催化剂通过需氧光氧化无过渡金属合成β-烷氧基单氢过氧化物的方法。该方法能够合成一些新颖的氢过氧化物。过氧化物源是分子氧,具有成本效益和原子效率。氧化镁在催化体系中起着重要的作用。
更新日期:2018-02-01
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