The solid‐state structure and Raman spectrum of Wannagat's mercurane, Hg[N(SiMe₃)₂]₂ (1), are reported. Crystals were grown from the pure substance by slow cooling to –24 °C. Compound 1 crystallizes in the monoclinic space group P2₁/c as discrete monomers, which do not display intermolecular mercurophilic interactions. The molecular structure features a nearly linear N–Hg–N scaffold, while the (Me₃Si)₂N groups are in a staggered conformation with a dihedral angle of 58.3° (average) to each other. This can be attributed to intramolecular dispersion interactions according to DFT calculations.

中文翻译：

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分散有所作为– Hg [N（SiMe3）2] 2的固态结构

报告了Wannagat硫醇Hg [N（SiMe ₃）₂ ] ₂（1）的固态结构和拉曼光谱。通过缓慢冷却至–24°C，从纯物质中生长出晶体。化合物1在单斜空间群P 2 ₁ / c中以离散单体的形式结晶，这些单体不显示分子间的嗜汞相互作用。分子结构具有近乎线性的N–Hg–N支架，而（Me ₃ Si）₂N个基团呈交错构型，彼此的二面角为58.3°（平均）。这可以归因于根据DFT计算的分子内分散相互作用。