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Ce0.7Bi0.3O1.85-(La0.8Sr0.2)0.9MnO3-Y0.16Zr0.84O1.92 ternary cathodes for low temperature solid oxide fuel cells
International Journal of Hydrogen Energy ( IF 7.2 ) Pub Date : 2018-01-11 , DOI: 10.1016/j.ijhydene.2017.12.130
Lei Shang , Zhe Zhao , Xiaomin Zhang , Zhidong Huang , Huiying Qi , Mojie Cheng

The ternary cathodes of Ce0.7Bi0.3O1.85-(La0.8Sr0.2)0.9MnO3-Y0.16Zr0.84O1.92 (BDC-LSM-YSZ) are fabricated through infiltration for low temperature solid oxide fuel cells. The infiltrated BDC particles are 10–20 nm in size and cover on LSM and YSZ particles. The 10 wt% and 20 wt% BDC-LSM-YSZ samples show a large peak for the desorption of surface oxygen species and a large peak for the evolution of lattice oxygen, reflecting their good redox property. 0.1BDC-LSM-YSZ cell and 0.2BDC-LSM-YSZ cell give the power density at 0.6 V of 387.8 and 521.7 mWcm−2 at 600 °C, which is 3.7 and 4.9 times higher than that of LSM-YSZ cell, respectively. 0.1BDC-LSM-YSZ cell and 0.2BDC-LSM-YSZ cell exhibit low ohmic resistance and low total polarization resistance. The DRT analysis reveals that charge transfer reaction and surface diffusion are greatly accelerated on the BDC-LSM-YSZ cathodes.



中文翻译:

Ce 0.7 Bi 0.3 O 1.85-(La 0.8 Sr 0.20.9 MnO 3 -Y 0.16 Zr 0.84 O 1.92低温固体氧化物燃料电池的三元阴极

通过渗入制备用于低温固体氧化物燃料电池的Ce 0.7 Bi 0.3 O 1.85-(La 0.8 Sr 0.20.9 MnO 3 -Y 0.16 Zr 0.84 O 1.92(BDC-LSM-YSZ)三元阴极。渗透的BDC颗粒大小为10–20 nm,覆盖在LSM和YSZ颗粒上。BDC-LSM-YSZ样品的10 wt%和20 wt%显示了一个较大的表面氧物质解吸峰和一个析出晶格氧的大峰,反映了它们良好的氧化还原性能。0.1BDC-LSM-YSZ电池和0.2BDC-LSM-YSZ电池在0.6 V时的功率密度为387.8和521.7 mWcm -2在600°C下,分别是LSM-YSZ电池的3.7和4.9倍。0.1BDC-LSM-YSZ电池和0.2BDC-LSM-YSZ电池表现出低欧姆电阻和低总极化电阻。DRT分析表明,在BDC-LSM-YSZ阴极上,电荷转移反应和表面扩散得到了极大的促进。

更新日期:2018-01-11
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