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Volumetric and viscometric properties of aqueous solutions of sodium amino acids at T = (293.15 to 333.15) K
Journal of Molecular Liquids ( IF 6 ) Pub Date : 2018-01-11 , DOI: 10.1016/j.molliq.2018.01.058
Chunyan Chu , Chunying Zhu , Taotao Fu , Youguang Ma

The densities and viscosities of aqueous solutions of sodium glycinate, sodium l-alaninate, sodium l-valinate, sodium l-threoninate and sodium l-argininate were measured at T = (293.15 to 333.15) K under the atmospheric pressure. The effects of temperature and concentration on the densities and viscosities of binary solutions were investigated. The volumetric and viscometric properties such as the apparent molar volume (Vφ), the limiting partial molar volume (Vφ0), the viscosity B-coefficient (B) and the activation energy for viscous flow (Ea) were calculated by the experimental density and viscosity data and analyzed based on the molecular structure and intermolecular interaction. Moreover, the group contribution method was utilized to study the limiting partial molar volume (Vφ0), and the contributions of the end group (-NH2,-COONa), CH- group, CH2- group, CH3- group, OH- group and CNHNHNH2- group to the limiting partial molar volume (Vφ0) were obtained. The results show that all these groups have positive contributions to the limiting partial molar volume (Vφ0).



中文翻译:

钠氨基酸水溶液在T  =(293.15至333.15)K时的体积和粘度特性

 在大气压下在T=(293.15至333.15)K下测量甘氨酸钠,1-丙氨酸钠,1-戊氨酸钠,1-苏氨酸钠和1-精氨酸钠水溶液的密度和粘度。研究了温度和浓度对二元溶液密度和粘度的影响。的体积和粘度性能,如表观摩尔体积(V φ),所述限制部分摩尔体积(V φ 0),粘度-coefficient()和粘性流动活化能(EA)是根据实验密度和粘度数据计算得出的,并根据分子结构和分子间的相互作用进行了分析。此外,所述基团贡献法被用来研究的限制部分摩尔体积(V φ 0),和端基的贡献(-NH 2,-COONa),CH-基,CH 2 -基,CH 3 -基团,OH-基团和CNHNHNH 2 -基团与限制部分摩尔体积(V φ 0获得)。结果表明,所有这些基团具有与限制部分摩尔体积(积极贡献V φ 0)。

更新日期:2018-01-11
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