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Organic Geochemistry and Depositional Environment of the Oltu Gemstone (Coal) in the Erzurum Area, NE Anatolia, Turkey
Energy & Fuels ( IF 5.3 ) Pub Date : 2018-01-24 00:00:00 , DOI: 10.1021/acs.energyfuels.7b03486
Reyhan Kara-Gülbay 1 , Sadettin Korkmaz 1 , Gülten Yaylalı-Abanuz 1 , M. Samet Erdoğan 1
Affiliation  

The Oltu Gemstone is located in the north of Oltu town (Erzurum–NE Turkey) city as a low rank coal. The Oltu Gemstone occurs as lenticular forms with thickness not exceeding centimeter size and lateral continuity of a few meters within the Liassic–Lower Malm Olurdere Formation consisting chiefly of claystone, sandstone, and volcanics. Coals that are operated as Oltu Gemstone are represented by very high TOC (67.39–78.56% wt), high hydrogen index (HI) values (314–379 mg HC/g TOC) and very low oxygen index (OI) values (1–3 mg CO2/g TOC). Low Pr/Ph ratios indicate that coals were prevented from oxidation and deposited under anoxic conditions. In Oltu Gemstone samples, C29 dominates over C27 and C28 steranes. In general, high (C19 + C20)/C23 tricyclic terpane, low Ts/(Ts + Tm), diasterane/sterane, and C31R/C30 hopane ratios were recorded. C29 MA steroids dominate with respect to others, and the C29/(C28 + C29) MA ratio is mostly high. DBT/P ratio of Oltu Gemstone samples has low values. Tmax values of Oltu Gemstone samples (between 416 and 436 °C) reflect immature–early mature character. 22S/(22R + 22S) homohopane, 20S/(20R + 20S), and ββ/(αα + ββ) sterane ratios and low moretane/hopane ratios, relatively high C28-TA/(C29-MA + C28-TA), MA(I)/MA(I + II), TA(I)/TA(I + II), MPI-3 (β/α MP), and MDR ratios indicate early mature character for the Oltu Gemstone samples.

中文翻译:

土耳其安那托利亚东北部埃尔祖鲁姆地区奥尔图宝石(煤)的有机地球化学和沉积环境

奥尔图(Oltu)宝石位于奥尔图镇(埃尔祖鲁姆–土耳其东北)北部,为低品位煤。奥尔图(Loltu)宝石以透镜状形式出现,厚度不超过厘米大小,并且在主要由粘土岩,砂岩和火山岩组成的Liassic-Lower Malm Olurdere组内具有几米的横向连续性。用作奥尔图宝石的煤具有极高的总有机碳(67.39-78.56%wt),高的氢指数(HI)值(314-379 mg HC / g TOC)和极低的氧指数(OI)值(1- 3 mg CO 2 / g TOC)。低的Pr / Ph比表明,可以防止煤炭在缺氧条件下发生氧化和沉积。在奥尔图(Oltu)宝石样品中,C 29比C 27和C 28甾烷占优势。一般而言,高(C记录了19 + C 20)/ C 23三环戊烷,低Ts /(Ts + Tm),非甾烷/甾烷和C 31 R / C 30 hop烷的比率。C 29 MA类固醇相对于其他类固醇占主导地位,并且C 29 /(C 28 + C 29)MA类比大部分较高。奥尔图宝石样品的DBT / P比值较低。Oltu宝石样品的T max值(介于416和436°C之间)反映了未成熟的早期特征。22S /(22R + 22S)同庚烷,20S /(20R + 20S)和ββ/(αα+ββ)甾烷比率和较低的茂铁/烷比率,相对较高的C 28 -TA /(C 29 -MA + C 28-TA),MA(I)/ MA(I + II),TA(I)/ TA(I + II),MPI-3(β/αMP)和MDR比表明Oltu宝石样品的早期成熟特征。
更新日期:2018-01-24
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