Unraveling the mystery of “tech red” – a volatile technetium oxide,Chemical Communications

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Unraveling the mystery of “tech red” – a volatile technetium oxide
Chemical Communications ( IF 4.9 ) Pub Date : 2018-01-10 00:00:00 , DOI: 10.1039/c7cc09191e
K. V. Lawler _{1,

2,

3,

4,

5} , B. C. Childs _{1,

2,

3,

4} , K. R. Czerwinski _{1,

2,

3,

4} , A. P. Sattelberger _{4,

6,

7,

8} , F. Poineau _{1,

2,

3,

4} , P. M. Forster _{1,

2,

3,

4,

5}

Affiliation

We show that a Tc₂O₅ molecular species is the likely identity of an unknown volatile oxide which has remained uncharacterized for 50+ years. Exploration of this molecule's absorption spectra and intermolecular self-interactions provides a close match to experimental data and an explanation for volatility and resistance to crystallization.

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