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Highly Efficient Catalytic Oxidation of Inert C(sp3)–H Bonds by the Synergistic Effect of Copper Nanoparticles/N‐Doped Graphene
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2018-03-05 , DOI: 10.1002/ejoc.201701286
Wei Sun 1 , Lingfeng Gao 1 , Xue Feng 1 , Xu Sun 1 , Gengxiu Zheng 1
Affiliation  

Using the synergistic effect of Cu nanoparticles (NPs) and N‐doped graphene, we report a highly efficient, green, and recyclable heterogeneous catalytic system for the functionalization of inert C(sp3)–H bonds with oxygen; this system has significantly higher activity than the N‐free Cu catalyst. The synergistic effect of the Cu NPs and N‐doped graphene is also unambiguously elucidated.
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中文翻译:

铜纳米粒子/ N掺杂石墨烯的协同效应对惰性C(sp3)–H键的高效催化氧化

利用铜纳米颗粒(NPs)和N掺杂石墨烯的协同效应,我们报道了一种高效,绿色和可循环利用的非均相催化体系,用于惰性C(sp 3)-H键与氧的功能化;该系统比不含N的Cu催化剂具有更高的活性。Cu NP和N掺杂的石墨烯的协同作用也得到明确阐明。
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更新日期:2018-03-05
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