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Stable meso-Fluorenyl Smaragdyrin Monoradical
Organic Letters ( IF 5.2 ) Pub Date : 2018-01-10 00:00:00 , DOI: 10.1021/acs.orglett.7b03784
Hemanta Kalita 1 , Tullimilli Y. Gopalakrishna 1 , Jishan Wu 1
Affiliation  

The facile synthesis and physical characterization of a meso-fluorenyl smaragdyrin monoradical 4, which is stable due to efficient spin delocalization and kinetic blocking, is reported. It has a small energy gap and can be oxidized and reduced into the respective cation and anion, showing different charge distribution and electronic absorption properties.

中文翻译:

稳定的内消旋-氟烯基Smaragdyrin单自由基

的简便合成和的物理表征内消旋-芴smaragdyrin单价4,其是稳定的,由于高效的自旋离域和动力学阻挡报道。它的能隙小,可以被氧化还原成各自的阳离子和阴离子,表现出不同的电荷分布和电子吸收特性。
更新日期:2018-01-10
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