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Omnidirectional and Broadband Light Absorption Enhancement in 2-D Photonic-Structured Organic Solar Cells
ACS Photonics ( IF 7 ) Pub Date : 2018-01-09 00:00:00 , DOI: 10.1021/acsphotonics.7b01573
Weixia Lan 1 , Yiwen Wang 2 , Jai Singh 3 , Furong Zhu 2
Affiliation  

The effect of 2-D photonic structures on omnidirectional and broadband light absorption enhancement in organic solar cells (OSCs) is analyzed using a combination of theoretical simulation and experimental optimization. The photonic structures in the active layer, with a blend system of poly[4,8-bis[(2-ethylhexyl)oxy] benzo[1,2-b:4,5-bA]dithiophene-2,6-diyl][3-fluoro-2-[(2- ethylhexyl)carbonyl]thieno[3,4-b]-thiophenediyl]:[6,6]-phenyl-C70- butyric-acid-methyl-ester (PTB7:PC70BM), were prepared by the nanoimprint method. It shows that the 2-D photonic structures enable not only broadband but also omnidirectional absorption enhancements in the PTB7:PC70BM-based OSCs over a broader angle range of the incident light, leading to >11% increase in the power conversion efficiency, as compared to an optimal planar control cell. A weak angular dependency on light absorption is a unique feature of the photonic-structured OSCs, which is useful for different applications.

中文翻译:

二维光子结构有机太阳能电池的全向和宽带光吸收增强

结合理论模拟和实验优化,分析了二维光子结构对有机太阳能电池(OSC)全方位和宽带光吸收增强的影响。活性层中的光子结构,具有聚[4,8-双[(2-乙基己基)氧基]苯并[1,2- b:4,5 - b A]二噻吩-2,6-二基的共混体系] [3-氟-2-[((2-乙基己基)羰基]噻吩并[3,4- b ]-噻吩二基] :[6,6]-苯基-C70-丁酸甲酯(PTB7:PC 70 BM),是通过纳米压印法制备的。结果表明,二维光子结构不仅可以实现宽带传输,而且还可以增强PTB7:PC 70的全向吸收能力与最佳平面控制单元相比,基于BM的OSC在更宽的入射光角度范围内,导致功率转换效率提高了11%以上。对光吸收的弱角度依赖性是光子结构OSC的独特功能,可用于不同的应用。
更新日期:2018-01-09
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