当前位置: X-MOL 学术Chem. Commun. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Visible-light-induced multicomponent cascade cycloaddition involving N-propargyl aromatic amines, diaryliodonium salts and sulfur dioxide: rapid access to 3-arylsulfonylquinolines
Chemical Communications ( IF 4.9 ) Pub Date : 2018-01-09 00:00:00 , DOI: 10.1039/c7cc09410h
Deli Sun 1, 2, 3, 4, 5 , Kun Yin 1, 2, 3, 4, 5 , Ronghua Zhang 1, 2, 3, 4, 5
Affiliation  

A visible-light-induced, Eosin Y catalyzed three-component synthesis of 3-arylsulfonylquinoline derivatives through N-propargyl aromatic amines, diaryliodonium salts and sulfur dioxide has been discovered. This transformation represents an efficient and attractive method for the straightforward synthesis of 3-arylsulfonylquinoline derivatives via the formation of C–S bonds and quinolines in one step. In addition, it exhibits good substrate scope and functional group tolerance. The use of easy-to-handle diaryliodonium salts, sulfur dioxide sources and the cheap photocatalyst Eosin Y together with facile operation at room temperature makes this protocol very practical.

中文翻译:

可见光诱导的多组分级联环加成反应,涉及N-炔丙基芳族胺,二芳基碘鎓盐和二氧化硫:快速获得3-芳基磺酰基喹啉

已经发现了可见光诱导的曙红Y通过N-炔丙基芳族胺,二芳基碘鎓盐和二氧化硫催化的3-芳基磺酰基喹啉衍生物的三组分合成。这种转变代表了通过一步形成C–S键和喹啉直接合成3-芳基磺酰基喹啉衍生物的一种有效且有吸引力的方法。另外,它表现出良好的底物范围和官能团耐受性。易处理的二芳基碘鎓盐,二氧化硫源和廉价的光催化剂曙红Y的使用以及在室温下的简便操作,使该方案非常实用。
更新日期:2018-02-02
down
wechat
bug