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Visible‐Light‐Promoted Synthesis of 1,4‐Dicarbonyl Compounds via Conjugate Addition of Aroyl Chlorides
Chemistry - An Asian Journal ( IF 4.1 ) Pub Date : 2018-01-17 , DOI: 10.1002/asia.201701738
Chao-Ming Wang 1 , Dan Song 1 , Peng-Ju Xia 1 , Jing Wang 1 , Hao-Yue Xiang 1 , Hua Yang 1
Affiliation  

A facile visible‐light photocatalytic conjugate addition to prepare 1,4‐dicarbonyl compounds has been developed by employing readily available aroyl chlorides as aryl radical sources. This operationally simple method shows a broad scope with regard to both aroyl chlorides and Michael acceptors. As a result, a variety of 1,4‐diketones were efficiently synthesized in moderate to good yields.

中文翻译:

通过芳酰氯的共轭添加,可见光促进1,4-二羰基化合物的合成

通过使用容易获得的芳酰氯作为芳基自由基来源,已经开发了一种简便的可见光光催化共轭加成物,用于制备1,4-二羰基化合物。对于芳酰氯和迈克尔受体,这种操作简单的方法显示了广泛的范围。结果,有效地合成了各种1,4-二酮,收率中等至良好。
更新日期:2018-01-17
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