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Coumarin Derivative Directly Coordinated to Lanthanides Acts as an Excellent Antenna for UV–Vis and Near-IR Emission
Inorganic Chemistry ( IF 4.6 ) Pub Date : 2018-01-08 00:00:00 , DOI: 10.1021/acs.inorgchem.7b02861
Óscar Guzmán-Méndez 1 , Federico González 2 , Sylvain Bernès 3 , Marcos Flores-Álamo 1 , Javier Ordóñez-Hernández 1 , Héctor García-Ortega 1 , Joselin Guerrero 1 , Wenjie Qian 4 , Nuria Aliaga-Alcalde 4, 5 , Laura Gasque 1
Affiliation  

A chelating coumarin-derived ligand sensitizes all emitting lanthanide ions in the solid state and gives high absolute quantum yields for ethanol solutions of complexes of Sm, Eu, Tb, and Dy, above 20% for the last two. Crystal structures of these four complexes are [Ln(Cum)3(H2O)(X)]·X where X = MeOH or EtOH.

中文翻译:

直接与镧系元素配位的香豆素衍生物可作为UV-Vis和近红外发射的出色天线

螯合的香豆素衍生的配体可敏化固态的所有发射镧系元素离子,并为Sm,Eu,Tb和Dy的复合物的乙醇溶液提供高的绝对量子产率,对于后两者来说,均超过20%。这四种络合物的晶体结构为[Ln(Cum)3(H 2 O)(X)]·X,其中X = MeOH或EtOH。
更新日期:2018-01-08
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