A transition metal- and organophotocatalyst-free hydroxylperfluoroalkylation of styrenes under visible-light irradiation was developed. In this protocol, an electron donor–acceptor complex (perfluoroalkyl iodide and tertiary amine) was employed for the introduction of a perfluorinated chain and molecular oxygen was used as a green oxidant for the generation of hydroxyl groups. Various styrenes successfully undergo the reaction affording the corresponding fluorine-containing alcohols in up to 96% yields.

中文翻译：

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苯乙烯的光诱导羟基全氟烷基化†

开发了可见光下苯乙烯无过渡金属和有机光催化剂的羟基全氟烷基化反应。在该协议中，电子给体-受体配合物（全氟烷基碘和叔胺）被用于引入全氟链，而分子氧被用作绿色氧化剂以产生羟基。各种苯乙烯成功地进行了反应，以高达96％的收率提供了相应的含氟醇。