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A mononuclear manganese(III)–hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions
Chemical Communications ( IF 4.9 ) Pub Date : 2018-01-08 00:00:00 , DOI: 10.1039/c7cc09492b
Muniyandi Sankaralingam 1, 2, 3 , Yong-Min Lee 1, 2, 3 , So Hyun Jeon 1, 2, 3 , Mi Sook Seo 1, 2, 3 , Kyung-Bin Cho 1, 2, 3 , Wonwoo Nam 1, 2, 3
Affiliation  

We report the synthesis of manganese(III)–peroxo (MnIII(O2)) and manganese(III)–hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(III)–hydroperoxo complex in electrophilic and nucleophilic reactions.

中文翻译:

单核锰(III)-氢过氧配合物:通过激活双氧的合成以及亲电和亲核反应中的反应性

我们报告了锰(III)-过氧(Mn III(O 2))和锰(III)-氢过氧(Mn III(O 2 H))配合物的合成,方法是通过激活双氧(O 2)和Mn的两性反应性(III)-亲电子和亲核反应中的氢过氧配合物。
更新日期:2018-01-31
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