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An Anionic Uranium-Based Metal–Organic Framework with Ultralarge Nanocages for Selective Dye Adsorption
Crystal Growth & Design ( IF 3.8 ) Pub Date : 2018-01-10 00:00:00 , DOI: 10.1021/acs.cgd.7b01525
Falu Hu 1, 2 , Zhengyi Di 1, 3 , Peng Lin 1, 2 , Pan Huang 1, 2 , Mingyan Wu 1 , Feilong Jiang 1 , Maochun Hong 1
Affiliation  

We herein present a rarely seen (3,4)-connected non-interpenetrated anionic uranium-organic framework with tbo topology (FJI–H-U1), which is constructed from two kinds of ultralarge nanocages. More importantly, FJI–H-U1 can selectively adsorb positively charged organic dyes Ethyl Violet, Janus Green B, and Rhodamine B over the anionic organic dye Methyl Orange due to the nature of its anionic framework.

中文翻译:

阴离子铀基金属有机骨架,具有超大纳米笼,可选择性吸附染料。

我们在这里展示了一种罕见的(3,4)连接的具有tbo拓扑结构的非互穿阴离子铀-有机骨架(FJI-H-U1),该骨架由两种超大型纳米笼构造而成。更重要的是,由于其阴离子骨架的性质,FJI–H-U1可以选择性地将带正电的有机染料乙基紫,剑叶绿B和若丹明B吸附在阴离子有机染料甲基橙上。
更新日期:2018-01-10
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