当前位置: X-MOL 学术J. Mol. Liq. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Interfacial tensions of pyridinium-based ionic liquids and n-alkanes or n-alkanols
Journal of Molecular Liquids ( IF 6 ) Pub Date : 2018-01-04 , DOI: 10.1016/j.molliq.2018.01.017
Andrea Moneo , Víctor Antón , Santiago Martín , Ignacio Gascón , Carlos Lafuente

Interfacial tensions of sixteen systems (pyridinium-based ionic liquid + n-alkane or n-alkanol) have been measured in the temperature range (283.15–313.15) K and at pressure of 0.1 MPa. The ionic liquids used were: 1-butylpyridinium tetrafluoroborate, 1-butyl-2-methylpyridinium tetrafluoroborate, 1-butyl-3-methylpyridinium tetrafluoroborate, and 1-butyl-4-methylpyridinium tetrafluoroborate. On the other hand, the organic solvents were: n-hexane, n-octane, n-hexanol, and n-octanol. The surface tensions of the organic liquids were also measured. The interfacial tensions for the systems involving n-alkanes are higher than for the systems containing n-alkanols. All the interfacial tensions decrease linearly with temperature. In addition the results have been interpreted using the equation proposed by Girifalco and Good.



中文翻译:

吡啶鎓离子液体与构烷烃或构烷醇的界面张力

16个系统的界面张力(基于吡啶鎓离子液体+  ñ烷烃或ñ链烷醇)已在温度范围(283.15-313.15)K,并在0.1MPa的压力被测量。所使用的离子液体为:四氟硼酸1-丁基吡啶鎓,四氟硼酸1-丁基-2-甲基吡啶鎓,四氟硼酸1-丁基-3-甲基吡啶鎓和四氟硼酸1-丁基-4-甲基吡啶鎓。在另一方面,所述有机溶剂为:Ñ己烷,Ñ辛烷,Ñ己醇,和Ñ辛醇。还测量了有机液体的表面张力。包含构烷烃的系统的界面张力高于包含构烷烃的系统的界面张力链烷醇。所有的界面张力都随温度线性降低。另外,已经使用Girifalco和Good提出的方程式解释了结果。

更新日期:2018-01-04
down
wechat
bug