Through a radical solvothermal polymerization method, we synthesized two porous organic polymers based on Tröger's base (POP‐TB and POP‐Me‐TB) from the corresponding vinyl‐functionalized monomers (2,8‐divinyl‐6H,12H‐5,11‐methanodibenzo[b,f]diazocine and 2,8‐divinyl‐4,10‐dimethly‐6H,12H‐5,11‐ethanodibenzo[b,f]diazocine; v‐TB and v‐Me‐TB). The structure and porosity of these polymers are verified by using solid‐state NMR spectroscopy, elemental analysis, SEM, TEM, N₂ sorption isotherms, and CO₂ sorption tests. They exhibit high surface areas and moderate pore volumes, which give high CO₂ adsorption capacities (90 and 71 mg g⁻¹ at 273 K and 60 and 44 mg g⁻¹ at 298 K for POP‐TB and POP‐Me‐TB, respectively) under a CO₂ pressure of 1 bar. In addition, they display excellent catalytic activities together with highly stability as heterogeneous catalysts in the benchmark Knoevenagel reactions.

中文翻译：

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由Tröger碱构造的多孔有机聚合物，可作为高效的二氧化碳吸附剂和非均相催化剂

通过自由基溶剂热聚合方法，我们从相应的乙烯基官能化单体（2,8-二乙烯基-6 H，12 H- 5， 11-甲基二苯并[ b，f ]重氮电影和2,8-二乙烯基-4,10-二甲基-6 H，12 H -5,11-乙二苯并[ b，f ]重氮电影; v-TB和v-Me-TB 。通过使用固态NMR光谱，元素分析，SEM，TEM，N ₂吸附等温线和CO ₂验证了这些聚合物的结构和孔隙率吸附测试。它们具有较高的表面积和适中的孔体积，可提供较高的CO ₂吸附能力（对于POP-TB和POP-Me-TB，在273 K时分别为90和71 mg g ^-1，在298 K时分别为60和44 mg g ^-1，分别在1 bar的CO ₂压力下进行。此外，它们在基准Knoevenagel反应中具有出色的催化活性以及作为非均相催化剂的高度稳定性。