Crystallization temperatures (liquidus and solidus) in the LiCl-Li₂O and (LiCl-KCl)-Li₂O systems with the KCl content of 10 and 20 mol.% were obtained with independent methods of thermal analysis using cooling curves, isothermal saturation, and differential scanning calorimetry. The linear sweep voltammetry was applied to control the time of the equilibrium establishment in the molten system after the Li₂O addition, which depended on the composition of the base melt and the concentration of Li₂O. The fragments of the binary LiCl-Li₂O and quazi-binary [LiCl-KCl(10 mol.%)]-Li₂O and [LiCl-KCl(20 mol.%)]-Li₂O phase diagrams in the Li₂O concentration range from 0 to 12 mol.% were obtained. The KCl presence in the LiCl-KCl-Li₂O molten mixture in the amount of 10 and 20 mol.% reduces the liquidus temperature by 30 and 80°, respectively, but the region of the homogeneous molten state of the system is considerably narrowed, which complicates its practical application. The Li₂O solubility in the molten LiCl, LiCl-KCl(10 mol.%) and LiCl-KCl(20 mol.%) decreases with increasing the KCl content and is equal to 11.5, 7.7 and 3.9 mol.% at 650°С, respectively. The LiCl-KCl melt with 10 mol.% KCl can be recommended for practical use as a medium for the SNF pyro-chemical reprocessing at temperature below 700 °C.

使用冷却曲线，等温饱和度的独立热分析方法，获得了KCl含量分别为10和20 mol。％的LiCl-Li ₂ O和（LiCl-KCl）-Li ₂ O系统中的结晶温度（液相线和固相线）和差示扫描量热法。Li ₂ O加入后，采用线性扫描伏安法控制熔融体系中平衡建立的时间，这取决于基础熔体的组成和Li ₂ O的浓度。二元LiCl-Li的碎片₂ O和自动准二进制[氯化锂-氯化钾（10摩尔％。）] -李₂ O和[氯化锂-氯化钾（20摩尔％。）] -李₂的李O相图₂O的浓度范围为0至12摩尔％。LiCl-KCl-Li ₂ O熔融混合物中KCl的存在量分别为10和20 mol。％，会使液相线温度分别降低30和80°，但是系统的均匀熔融状态区域明显变窄，使其实际应用复杂化。Li ₂ O在熔融LiCl，LiCl-KCl（10 mol。％）和LiCl-KCl（20 mol。％）中的溶解度随KCl含量的增加而降低，在650°下等于11.5、7.7和3.9 mol。％ С。推荐将含10 mol。％KCl的LiCl-KCl熔体实际用作温度低于700°C时SNF热化学后处理的介质。