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Selective hydrogenation of nitroarenes using an electrogenerated polyoxometalate redox mediator
Chemical Communications ( IF 4.9 ) Pub Date : 2018-01-04 00:00:00 , DOI: 10.1039/c7cc09036f Lewis MacDonald 1, 2, 3, 4, 5 , Benjamin Rausch 1, 2, 3, 4, 5 , Mark D. Symes 1, 2, 3, 4, 5 , Leroy Cronin 1, 2, 3, 4, 5
Chemical Communications ( IF 4.9 ) Pub Date : 2018-01-04 00:00:00 , DOI: 10.1039/c7cc09036f Lewis MacDonald 1, 2, 3, 4, 5 , Benjamin Rausch 1, 2, 3, 4, 5 , Mark D. Symes 1, 2, 3, 4, 5 , Leroy Cronin 1, 2, 3, 4, 5
Affiliation
The 2-electron reduced form of the polyoxometalate silicotungstic acid (H4[SiW12O4]) is shown to be an effective and selective hydrogenation agent for a range of nitroarenes without the need for any co-catalyst. The ease of generation of the active species and its recyclability suggest that a new approach to this important class of chemical conversions is possible.
中文翻译:
使用电生成的多金属氧酸盐氧化还原介体对硝基芳烃进行选择性加氢
已显示多氧合金属酸盐硅钨酸(H 4 [SiW 12 O 4 ])的2-电子还原形式是一系列硝基芳烃的有效且选择性的氢化剂,而无需任何助催化剂。活性物种的易产生性及其可回收性表明,针对这种重要的化学转化类别的新方法是可能的。
更新日期:2018-01-25
中文翻译:
使用电生成的多金属氧酸盐氧化还原介体对硝基芳烃进行选择性加氢
已显示多氧合金属酸盐硅钨酸(H 4 [SiW 12 O 4 ])的2-电子还原形式是一系列硝基芳烃的有效且选择性的氢化剂,而无需任何助催化剂。活性物种的易产生性及其可回收性表明,针对这种重要的化学转化类别的新方法是可能的。