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Retracted Article: Insight into the reversible structural crystalline-state transformation from MIL-53(Al) to MIL-68(Al)†
CrystEngComm ( IF 3.1 ) Pub Date : 2018-01-03 00:00:00 , DOI: 10.1039/c7ce02034a
Adelaida Perea-Cachero 1, 2, 3, 4, 5 , Enrique Romero 1, 3, 4, 5, 6 , Carlos Téllez 1, 2, 3, 4, 5 , Joaquín Coronas 1, 2, 3, 4, 5
Affiliation  

The reversible crystalline transformation between MIL-53(Al) and MIL-68(Al) is described. This followed a uniform conversion model with cleavage and formation of metal–ligand bonds after exchange or removal of guest molecules. MIL-68(Al) materials produced during the transformations had higher thermal stability and crystallinity than the as-synthesized MIL-68(Al).

中文翻译:

缩回文章:洞悉从MIL-53(Al)到MIL-68(Al)的可逆结构结晶态转变

描述了MIL-53(A1)和MIL-68(A1)之间的可逆晶体转变。这遵循了一个统一的转换模型,其中交换或去除了客体分子后,金属-配体键断裂并形成。相变合成后的MIL-68(Al)材料比合成后的MIL-68(Al)具有更高的热稳定性和结晶度。
更新日期:2018-01-03
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