Fluorosulfates are readily available electrophiles that can be prepared from the reactions of phenol or alcohol derivatives with sulfuryl fluoride, fluorosulfonic acid, sulfuryl chloride fluoride, and fluorosulfonic anhydride. This Focus Review covers most of the synthetic strategies that have been reported for the construction of fluorosulfates, as well as their application as versatile building blocks in a variety of synthetic transformations, such as catalyzed amination, cross‐coupling, sulfur(VI) fluoride exchange, carbonylation, hydrolysis, alcoholysis, and as alternatives to organic halides or triflates in organic chemistry.

中文翻译：

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氟代硫酸盐的合成与化学转化

氟代硫酸盐是易于获得的亲电试剂，可以通过苯酚或醇衍生物与硫酰氟，氟磺酸，硫酰氯氟化物和氟磺酸酐的反应制得。本《聚焦评论》涵盖了已报道的用于构建氟代硫酸盐的大多数合成策略，以及它们在各种合成转化中作为通用构件的应用，例如催化胺化，交叉偶联，氟化硫（VI）交换，羰基化，水解，醇解，以及有机化学中有机卤化物或三氟甲磺酸酯的替代物。