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Iridium complexes with monodentate N-heterocyclic carbene ligands
Coordination Chemistry Reviews ( IF 20.6 ) Pub Date : 2017-12-27 , DOI: 10.1016/j.ccr.2017.10.019
Gellért Sipos , Reto Dorta

Monodentate N-heterocyclic carbene (NHC) ligands have been an extremely successful class of ancillary ligands in transition metal chemistry over the last 3 decades. Particularly important developments during that period have seen the use of bulky, monodentate NHC ligands in late transition metal chemistry and catalysis. In this review, we have gathered results that present how these monodentate ligands have been used in iridium chemistry. A comprehensive overview on synthetic methods available to access NHC–Ir compounds, the stoichiometric activity of the resulting complexes as well as their use in catalysis and other applications is given in the following pages.



中文翻译:

具有单齿N-杂环卡宾配体的铱配合物

在过去的30年中,单齿N-杂环卡宾(NHC)配体在过渡金属化学领域已成为一类非常成功的辅助配体。在此期间,特别重要的进展是在后期过渡金属化学和催化中使用了庞大的单齿NHC配体。在这篇综述中,我们收集了一些结果,介绍了这些单齿配体如何在铱化学中使用。以下页面全面概述了可用于获得NHC-Ir化合物的合成方法,所得络合物的化学计量活性以及它们在催化和其他应用中的用途。

更新日期:2018-06-03
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