Synthesis and mechanical exfoliation of imine-linked two-dimensional conjugated polymers†,Journal of Materials Chemistry C

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Synthesis and mechanical exfoliation of imine-linked two-dimensional conjugated polymers†
Journal of Materials Chemistry C ( IF 6.4 ) Pub Date : 2017-12-29 00:00:00 , DOI: 10.1039/c7tc04370h
Haining Liu _{1,

2,

3} , Qing Li _{4,

5,

6,

7} , Yiming Zhu _{1,

2,

3,

3,

8} , Mei Zhang _{1,

2,

3} , Runjing Liu _{4,

5,

6,

7} , Xiaoming Li _{4,

5,

6,

7} , Xiao Kang _{4,

5,

6,

7} , Zheng Li _{4,

5,

6,

7} , Shanlin Qiao _{4,

5,

6,

7}

Affiliation

For the first time, we report the synthesis of imine-linked crystalline conjugated covalent organic frames and their mechanical exfoliation into 2D sheets with thicknesses of 3–40 nm. Raman spectroscopy and atomic force microscopy have been used to characterize the exfoliated 2D polymer sheets. Electrical measurements have shown that the exfoliated 2D polymer sheets can be conductive after thermal and electrical annealing.

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