A robust sunlight-driven AgIO₃/MIL-53 (Fe) nanohybrid composite (NC) was successfully synthesised and characterised. The efficacy of the NC was estimated by decomposing two organophosphates pesticides (methyl malathion (MP) and chlorpyrifos (CP)) under sunlight irradiation. The degradation of MP and CP was strongly influenced by pH, catalyst dose and initial pesticide concentration. Under 60 min solar light illumination, ∼78–90% CP and MP were degraded individually in tap and distilled water, respectively. In binary mixture (MP + CP), ∼70% mineralisation was achieved within 180 min. The efficiency of NC is attributed to the prolonged separation of photogenerated carriers, a large concentration of surface hydroxyl groups and high specific surface area. Under artificial neural network (ANN) predicted conditions, 0.5 g NC, pH 5 and 2.5 mL of 50 mg/L Na₂S₂O₈ are required for complete mineralisation of the pesticides.

强大的阳光驱动AgIO ₃/ MIL-53（Fe）纳米杂化复合物（NC）已成功合成和表征。通过在阳光照射下分解两种有机磷酸酯农药（甲基马拉硫磷（MP）和毒死rif（CP））来评估NC的功效。MP和CP的降解受到pH，催化剂剂量和农药初始浓度的强烈影响。在60分钟的太阳光照射下，自来水和蒸馏水中的CP和MP分别降低约78-90％。在二元混合物（MP + CP）中，在180分钟内实现了约70％的矿化。NC的效率归因于光生载流子的延长分离，高浓度的表面羟基和高比表面积。在人工神经网络（ANN）预测的条件下，0.5 g NC，pH 5和2.5 mL的50 mg / L Na ₂S ₂ O ₈是农药完全矿化所必需的。