This study investigated for the first time the degradation of phenol, chlorophenol, fluorophenol and bisphenol A (BPA) by the novel iron phthalocyanine/spongin hybrid material under various process conditions: hydrogen peroxide and UV irradiation. The heterogeneous catalyst, iron phthalocyanine/spongin (SFe), was produced by an adsorption process. The product obtained was investigated by a variety of spectroscopic techniques – X-ray photoelectron spectroscopy (XPS), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR) and carbon-13 nuclear magnetic resonance (¹³C NMR) – as well as elemental and thermal analysis. The study confirmed the stable immobilization of the dye on the biopolymer. The results demonstrate that the degradation of phenols and BPA followed pseudo-second-order kinetics under different experimental conditions. The synergy of SFe, H₂O₂ and UV was found to produce a significant increase in the removal efficiency and resulted in complete removal of contaminants in a short time of 1 hour. The reaction products were identified by high-performance liquid chromatography/mass spectrometry (HPLC-MS) and possible degradation pathways were proposed, featuring a series of steps including cleavage of C–C bonds and oxidation.

这项研究首次研究了新型铁酞菁/海绵铁杂化材料在各种工艺条件下（过氧化氢和紫外线辐射下）对苯酚，氯酚，氟酚和双酚A（BPA）的降解。非均相催化剂，酞菁铁/海绵铁（SFe），是通过吸附工艺生产的。所获得的产品已通过多种光谱技术进行了研究-X射线光电子能谱（XPS），能量色散X射线能谱（EDS），傅里叶变换红外光谱（FTIR）和碳13核磁共振（¹³C NMR）–以及元素分析和热分析。研究证实了染料在生物聚合物上的稳定固定。结果表明，在不同的实验条件下，苯酚和BPA的降解遵循伪二级动力学。发现SFe，H ₂ O ₂和UV的协同作用可显着提高去除效率，并在短短的1小时内完全去除污染物。通过高效液相色谱/质谱（HPLC-MS）鉴定了反应产物，并提出了可能的降解途径，其特征是包括裂解C–C键和氧化的一系列步骤。