当前位置: X-MOL 学术Mater. Chem. Front. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Cost-effective synthesis and solution processing of porous polymer networks through methanesulfonic acid-mediated aldol triple condensation†
Materials Chemistry Frontiers ( IF 7 ) Pub Date : 2017-12-27 00:00:00 , DOI: 10.1039/c7qm00485k
Zi-Hao Guo 1, 2, 3, 4 , Chenxu Wang 2, 3, 4, 5 , Qiang Zhang 1, 4, 6, 7 , Sai Che 1, 2, 3, 4 , Hong-Cai Zhou 1, 2, 3, 4, 5 , Lei Fang 1, 2, 3, 4, 5
Affiliation  

A highly efficient aldol triple condensation method was developed for scalable synthesis of conjugated porous polymer networks. This bottom-up strategy features inexpensive starting materials and reagents as well as simple reaction procedures, which are ideal for mass production of functional organic porous materials. The resultant porous material demonstrated quick and selective adsorption of organic small molecules in aqueous solution. In addition, the pristine composition of the reaction mixture enabled solution processing of these cross-linked porous materials through a “soaking–heating–washing” procedure to form composite membranes that are essential for practical applications.

中文翻译:

通过甲磺酸介导的羟醛三重缩合反应,经济高效地合成和加工多孔聚合物网络

开发了一种高效的羟醛三重缩合方法,用于可扩展的共轭多孔聚合物网络合成。这种自下而上的策略以廉价的起始原料和试剂以及简单的反应程序为特征,是批量生产功能性有机多孔材料的理想选择。所得的多孔材料证明了有机小分子在水溶液中的快速选择性吸附。另外,反应混合物的原始组成使得这些交联的多孔材料能够通过“浸泡-加热-洗涤”程序进行溶液处理,以形成对于实际应用必不可少的复合膜。
更新日期:2017-12-27
down
wechat
bug