An enantioselective conjugate addition of 2‐acylimidazoles with nitroalkenes catalyzed by chiral‐at‐metal rhodium(III) complex under mild reaction conditions was developed, affording versatile γ‐nitro ketone skeletons in good yields with excellent enantioselectivities (up to >99% ee).

中文翻译：

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手性金属铑（III）配合物促进的2-乙酰咪唑与硝基烯烃的对映选择性共轭加成反应

开发了在温和的反应条件下手性金属铑（III）配合物催化的2-酰基咪唑与硝基烯烃的对映选择性共轭加成反应，提供了具有良好对映选择性（高达> 99％ee）的高产率的通用γ-硝基酮骨架。