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The Dibenzosuberenone Scaffold as a Privileged Substructure: From Synthesis to Application
Synthesis ( IF 2.6 ) Pub Date : 2017-12-21 , DOI: 10.1055/s-0036-1589518
Arif Dastan 1 , Nurullah Saracoglu 1 , Haydar Kilic 2
Affiliation  

This review is dedicated to Emeritus Professor Metin Balci (Ataturk University and Middle East Technical University) on behalf of all Balci students, past and present, with warmest congratulations, respect, and admiration, on the occasion of his 69th birthday.

Abstract

Numerous studies on dibenzosuberenones, especially on 5-dibenzosuberenones, have emerged in recent years. This review focuses on the chemistry of dibenzosuberenones, including their synthesis and applications, which are currently used as tools by the synthetic and biological communities.

1 Introduction

2 5-Dibenzosuberenone (5H-Dibenzo[a,d]cyclohepten-5-one)

2.1 Synthesis of 5-Dibenzosuberenone

2.2 Reactions of 5-Dibenzosuberenone

3 5H-Dibenzo[a,c]cyclohepten-5-one

3.1 Synthesis of 5H-Dibenzo[a,c]cyclohepten-5-one

3.2 Reactions of 5H-Dibenzo[a,c]cyclohepten-5-one

4 6H-Dibenzo[a,c]cyclohepten-6-one and 10H-Dibenzo[a,d]cyclohepten-10-one

4.1 Generation and Trapping of 6H-Dibenzo[a,c]cyclohepten-6-one and 10H-Dibenzo[a,d]cyclohepten-10-one

5 Dibenzocycloheptenediones

5.1 Synthesis of Dibenzocycloheptenediones

5.2 Reactions of Dibenzocycloheptenediones

6 Conclusion

Numerous studies on dibenzosuberenones, especially on 5-dibenzosuberenones, have emerged in recent years. This review focuses on the chemistry of dibenzosuberenones, including their synthesis and applications, which are currently used as tools by the synthetic and biological communities.

1 Introduction

2 5-Dibenzosuberenone (5H-Dibenzo[a,d]cyclohepten-5-one)

2.1 Synthesis of 5-Dibenzosuberenone

2.2 Reactions of 5-Dibenzosuberenone

3 5H-Dibenzo[a,c]cyclohepten-5-one

3.1 Synthesis of 5H-Dibenzo[a,c]cyclohepten-5-one

3.2 Reactions of 5H-Dibenzo[a,c]cyclohepten-5-one

4 6H-Dibenzo[a,c]cyclohepten-6-one and 10H-Dibenzo[a,d]cyclohepten-10-one

4.1 Generation and Trapping of 6H-Dibenzo[a,c]cyclohepten-6-one and 10H-Dibenzo[a,d]cyclohepten-10-one

5 Dibenzocycloheptenediones

5.1 Synthesis of Dibenzocycloheptenediones

5.2 Reactions of Dibenzocycloheptenediones

6 Conclusion



中文翻译:

作为优先子结构的Dibenzosuberenone支架:从合成到应用

这次审查是专门为名誉教授倚天巴尔西(阿塔图尔克大学和中东技术大学)代表全体学生巴尔西,过去和现在,用最热烈的祝贺,尊重和钦佩,他的69之际生日。

抽象的

近年来,已经出现了许多关于二苯并异戊二烯酮的研究,尤其是对5-二苯并异戊二烯酮的研究。这篇综述着重于二苯并双氢肾上腺素的化学,包括它们的合成和应用,目前已被合成和生物界用作工具。

1引言

2 5-二苯并异戊二烯酮(5 H-二苯并[ ad ]环庚-5-酮)

2.1合成5-Dibenzosuberenone

2.2 5-二苯并异戊二烯酮的反应

3 5 H-二苯并[ ac ]环庚-5-酮

3.1 5 H-二苯并[ ac ]环庚-5-酮的合成

3.2 5 H-二苯并[ ac ]环庚-5-酮的反应

4 6 H-二苯并[ ac ]环庚烯-6-和10 H-二苯并[ ad ]环庚烯-10-

4.1 6 H-二苯并[ ac ]环庚-6-1和10 H-二苯并[ ad ]环庚-10-10的生成和俘获

5二苯并环庚二烯

5.1二苯并环庚二酮的合成

5.2二苯并环庚二烯的反应

六,结论

近年来,已经出现了许多关于二苯并异戊二烯酮的研究,尤其是对5-二苯并异戊二烯酮的研究。这篇综述着重于二苯并双氢肾上腺素的化学,包括它们的合成和应用,目前已被合成和生物界用作工具。

1引言

2 5-二苯并异戊二烯酮(5 H-二苯并[ ad ]环庚-5-酮)

2.1合成5-Dibenzosuberenone

2.2 5-二苯并异戊二烯酮的反应

3 5 H-二苯并[ ac ]环庚-5-酮

3.1 5 H-二苯并[ ac ]环庚-5-酮的合成

3.2 5 H-二苯并[ ac ]环庚-5-酮的反应

4 6 H-二苯并[ ac ]环庚烯-6-和10 H-二苯并[ ad ]环庚烯-10-

4.1 6 H-二苯并[ ac ]环庚-6-1和10 H-二苯并[ ad ]环庚-10-10的生成和俘获

5二苯并环庚二烯

5.1二苯并环庚二酮的合成

5.2二苯并环庚二烯的反应

六,结论

更新日期:2017-12-21
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