当前位置: X-MOL 学术Cryst. Growth Des. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Temperature Dependence of the Growth Kinetics of Elementary Spiral Steps on Ice Basal Faces Grown from Water Vapor
Crystal Growth & Design ( IF 3.8 ) Pub Date : 2018-01-04 00:00:00 , DOI: 10.1021/acs.cgd.7b01251
Masahiro Inomata 1 , Ken-ichiro Murata 1 , Harutoshi Asakawa 1 , Ken Nagashima 1 , Shunichi Nakatsubo 1 , Yoshinori Furukawa 1 , Gen Sazaki 1
Affiliation  

We measured the velocity Vstep of isolated elementary spiral steps and the distance Leq between adjacent equivalent spiral steps on ice basal faces by advanced optical microscopy. We determined the step kinetic coefficient β from Vstep measured under various supersaturations. We performed similar experiments under various temperatures T, and determined the temperature dependence of β of ice basal faces, for the first time, in the temperature range of −26.0 to −2.7 °C. When −6.2 ≤ T ≤ −2.7 °C, the value of β decreased significantly with decreasing T. In contrast, when −15.0 ≤ T ≤ −6.2 °C, the value of β increased with decreasing T, and had the maximum at T ≈ −15 °C. When −26.0 ≤ T ≤ −15.0 °C, the value of β decreased monotonically with decreasing T. Such complicated temperature dependence of β strongly implies the existence of unknown phenomena in the temperature range examined. To obtain a clue to the complicated behavior of β, we also measured dependence of Leq on surface supersaturation Δμsurf. When −13.0 ≤ T ≤ −3.2 °C, plots of Leq vs 1/Δμsurf satisfactorily follow the spiral growth model. However, when −26.0 ≤ T ≤ −15.0 °C, the Leq vs 1/Δμsurf plots do not follow any model: this temperature range agrees with the temperature range in which β decreased monotonically with decreasing T.

中文翻译:

水蒸气生长的冰基面上基本螺旋台阶生长动力学的温度依赖性

我们测量了速度V步骤的分离的基本螺旋形的步骤和距离大号当量通过先进光学显微镜在冰上基底面相邻的等效螺旋步骤之间。我们从在各种过饱和条件下测得的V阶跃确定了阶跃动力学系数β 。我们在各种温度T下进行了类似的实验,并首次确定了冰基面β在-26.0至-2.7°C的温度范围内的温度依赖性。当-6.2≤T≤ - 2.7°C时,β值随着T的降低而显着降低。相反,当-15.0≤ Ť≤-6.2℃,β的值随增加Ť,并有最大在Ť ≈-15℃。当-26.0≤T≤ - 15.0°C时,β值随着T的降低而单调降低。β的这种复杂的温度依赖性强烈暗示在所检查的温度范围内存在未知现象。为了获得线索β的复杂行为,我们还测量的依赖大号当量上表面过饱和Δμ冲浪。当-13.0≤ Ť ≤-3.2℃,的曲线大号当量对1 / Δμ冲浪令人满意地跟随螺旋生长模型。但是,当-26.0≤时Ť ≤-15.0℃时,大号当量对1 / Δμ冲浪曲线不按照任何模型:该温度范围内与温度范围中β随单调减少同意Ť
更新日期:2018-01-04
down
wechat
bug