Two low-permittivity dielectric materials Li₂AGeO₄ (A = Zn, Mg) were prepared via the solid-state reaction method. X-ray diffraction analysis and Rietveld refinement indicated that both ceramics crystallize in an orthorhombic olivine structure with a space group Pmn2₁. Dense ceramics with high relative density and homogeneous microstructure were obtained. Li₂ZnGeO₄ densified at 1200 °C possessed a relative permittivity ε_r = 6.5, a quality factor Q × f = 35,400 GHz, and a temperature coefficient of resonant frequency. Li₂MgGeO₄ exhibited ε_r = 6.1, Q × f = 28,500 GHz, and τ_f = –74.7 ppm/°C when sintered at 1220 °C. Additionally, the large negative τ_f values of Li₂AGeO₄ (A = Zn, Mg) ceramics were successfully adjusted compensated by forming composite ceramics with CaTiO₃ and near-zero τ_f values of +2.9 ppm/°C and +5.8 ppm/°C were achieved in 0.92Li₂ZnGeO₄-0.08CaTiO₃ and 0.90Li₂MgGeO₄-0.10CaTiO₃, respectively.

通过固态反应法制备了两种低介电常数的电介质材料Li ₂ AGeO ₄（A = Zn，Mg）。X射线衍射分析和Rietveld精炼表明，两种陶瓷均以正交晶体橄榄石结构（空间群为Pmn2 _1）结晶。获得具有高相对密度和均质微观结构的致密陶瓷。李₂ ZnGeO ₄在1200致密化℃下所具有的相对介电常数ε _{- [R}  =  6.5，品质因数Q×˚F  = 35400千兆赫，及谐振频率的温度系数。李₂ MgGeO ₄显示出ε _{- [R} =  6.1，Q×˚F  = 28500千兆赫，和τ _˚F  = -74.7 PPM /℃时，在1220℃下烧结°。此外，该大的负τ _˚F李的值₂ AGEO ₄（A =锌，镁）陶瓷成功地调节通过用的CaTiO形成复合陶瓷补偿₃和接近零的τ _˚F 2.9 PPM的值/℃和5.8 ppm的/℃分别在0.92Li ₂ ZnGeO ₄ -0.08CaTiO ₃和0.90Li ₂ MgGeO ₄ -0.10CaTiO _3中实现。